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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">corrosionprotection</journal-id><journal-title-group><journal-title xml:lang="ru">Практика противокоррозионной защиты</journal-title><trans-title-group xml:lang="en"><trans-title>Theory and Practice of Corrosion Protection</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">1998-5738</issn><issn pub-type="epub">2658-6797</issn><publisher><publisher-name>Association "CARTEC"</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.31615/j.corros.prot.2023.110.4-5</article-id><article-id custom-type="elpub" pub-id-type="custom">corrosionprotection-104</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ПРИКЛАДНАЯ ЭЛЕКТРОХИМИЯ</subject></subj-group></article-categories><title-group><article-title>Электрохимическое (со)осаждение лантана и кобальта из растворов на основе триметилфосфата</article-title><trans-title-group xml:lang="en"><trans-title>Electrochemical (co)deposition of lanthanum and cobalt from trimethyl phosphate-based solutions</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Зайцев</surname><given-names>О. И.</given-names></name><name name-style="western" xml:lang="en"><surname>Zaytsev</surname><given-names>O. I.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Зайцев Олег Ильич, старший лаборант,</p><p>119071, г. Москва, Ленинский проспект, д. 31, корп. 4 .</p></bio><bio xml:lang="en"><p>Oleg I. Zaytsev, senior laboratory assistant,</p><p>bld. 4, 31, Leninskiy pr., Moscow, 119071.</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Черепаха</surname><given-names>А. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Cherepakha</surname><given-names>A. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Черепаха Анна Владимировна, студент, </p><p>125047, г. Москва, Миусская площадь, д. 9.</p></bio><bio xml:lang="en"><p>Anna V. Cherepakha, student, </p><p>9, Miusskaya square, Moscow, 125047.</p></bio><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Эренбург</surname><given-names>М. Р.</given-names></name><name name-style="western" xml:lang="en"><surname>Ehrenburg</surname><given-names>M. R.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Эренбург Мария Рудольфовна, к.х.н., в.н.с.,</p><p>119071, г. Москва, Ленинский проспект, д. 31, корп. 4 .</p></bio><bio xml:lang="en"><p>Maria R. Ehrenburg, PhD in Chemistry, leading researcher,</p><p>bld. 4, 31, Leninskiy pr., Moscow, 119071.</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Филиппов</surname><given-names>В. Л.</given-names></name><name name-style="western" xml:lang="en"><surname>Filippov</surname><given-names>V. L.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Филиппов Вадим Леонидович, аспирант, м.н.с.,</p><p>119071, г. Москва, Ленинский проспект, д. 31, корп. 4 .</p></bio><bio xml:lang="en"><p>Vadim L. Filippov, postgraduate student, junior researcher,</p><p>bld. 4, 31, Leninskiy pr., Moscow, 119071.</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Руднев</surname><given-names>А. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Rudnev</surname><given-names>A. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Руднев Александр Викторович, к.х.н., в.н.с.,</p><p>119071, г. Москва, Ленинский проспект, д. 31, корп. 4 .</p></bio><bio xml:lang="en"><p>Alexander V. Rudnev, PhD in Chemistry, leading researcher,</p><p>bld. 4, 31, Leninskiy pr., Moscow, 119071.</p></bio><email xlink:type="simple">rudnev@phyche.ac.ru</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Институт физической химии и электрохимии имени А.Н. Фрумкина РАН (ИФХЭ РАН)</institution><country>Россия</country></aff><aff xml:lang="en"><institution>A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of RAS</institution><country>Russian Federation</country></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru"><institution>Российский химико-технологический университет имени Д.И. Менделеева</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Dmitry Mendeleev University of Chemical Тесhпоlоgy of Russia</institution><country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2023</year></pub-date><pub-date pub-type="epub"><day>10</day><month>12</month><year>2023</year></pub-date><volume>28</volume><issue>4</issue><fpage>40</fpage><lpage>48</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Зайцев О.И., Черепаха А.В., Эренбург М.Р., Филиппов В.Л., Руднев А.В., 2023</copyright-statement><copyright-year>2023</copyright-year><copyright-holder xml:lang="ru">Зайцев О.И., Черепаха А.В., Эренбург М.Р., Филиппов В.Л., Руднев А.В.</copyright-holder><copyright-holder xml:lang="en">Zaytsev O.I., Cherepakha A.V., Ehrenburg M.R., Filippov V.L., Rudnev A.V.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://www.corrosion-protection.ru/jour/article/view/104">https://www.corrosion-protection.ru/jour/article/view/104</self-uri><abstract><p>Понимание процесса (со)осаждения лантаноидов является важным шагом к возможности их эффективного рециклинга и электрохимического формирования материалов на основе лантаноидов. Растущий интерес к органическим ионным системам, таким как ионные жидкости, обусловлен их превосходными физико-химическими свойствами, в частности – нелетучестью, термической и электрохимической стабильностью. Кроме того, органические ионные системы могут использоваться для экстракции лантаноидов. Таким образом, комбинированный процесс экстракции и электроосаждения имеет хорошие практические перспективы. В этой работе мы исследовали электрохимическое (со)осаждение лантана и кобальта из растворов на основе триметилфосфата (ТМФ). Показано, что при катодной поляризации Pt электрода в растворе Co(II) в ТМФ формируется зернистый осадок Co, в то время как в растворе La(III) в ТМФ осаждение La не наблюдали. Однако вольтамперометрические данные и данные микроскопии и элементного анализа указывают на то, что в растворе, содержащем как La(III), так и Co(II), происходит электрохимическое соосаждение Co и La. Сделан вывод, что в присутствии Co(II) в ТМФ происходит индуцирование электровосстановления ионов La(III).</p></abstract><trans-abstract xml:lang="en"><p>Understanding the process of lanthanide (co)deposition is an important step towards the possibility of their efficient recycling and the electrochemical formation of lanthanide-based materials. Growing interest in organic ionic systems such as ionic liquids is due to their excellent physicochemical properties, particularly nonvolatility, thermal and electrochemical stability. In addition, organic ionic systems can be used for the extraction of lanthanides. Thus, the combined process of extraction and electrodeposition has good prospects to practical purposes. In this work, we investigated the electrochemical (co)deposition of lanthanum and cobalt from trimethyl phosphate (TMP)-based solutions. It was shown that during cathodic polarization of a Pt electrode in a solution of Co(II) in TMP, a granular deposit of Co is formed, while no deposition of La was observed in a solution of La(III) in TMP. Nevertheless, voltammetric, microscopic, and elemental analysis data indicate that electrochemical codeposition of Co and La occurs in a solution containing both La(III) and Co(II). It is concluded that the presence of Co(II) in TMP induces the electroreduction of La(III) ions.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>лантаноид</kwd><kwd>триметилфосфат</kwd><kwd>электроосаждение</kwd><kwd>ионная жидкость</kwd><kwd>нейтральный лиганд</kwd></kwd-group><kwd-group xml:lang="en"><kwd>lanthanide</kwd><kwd>trimethyl phosphate</kwd><kwd>electrodeposition</kwd><kwd>ionic liquid</kwd><kwd>neutral ligand</kwd></kwd-group><funding-group><funding-statement xml:lang="ru">Исследование выполнено за счет гранта Российского научного фонда № 22-23- 00819, https://rscf.ru/project/22-23-00819/. 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