corrosionprotectionПрактика противокоррозионной защитыTheory and Practice of Corrosion Protection1998-57382658-6797Association "CARTEC"10.31615/j.corros.prot.2024.111.1-3corrosionprotection-114Research ArticleМАТЕРИАЛЫ И ОБОРУДОВАНИЕ ДЛЯ ПРОТИВОКОРРОЗИОННОЙ ЗАЩИТЫMATERIALS AND EQUIPMENT FOR CORROSION PROTECTIONИнгибирующие свойства отвара мелиссы лекарственной (Melissa officinalis) против коррозии низкоуглеродистой стали в сернокислых средахThe Inhibitory Properties of Lemon Balm (Melissa officinalis) Boiling Extract on the Corrosion of Mild Steel in Sulphuric Acid MediumНиколайчукП. А.NikolaychukP. A.

Павел Анатольевич Николайчук, м. н. с.

научно-исследовательская лаборатория «Перспективные материалы для индустрии и биомедицины»

640020; ул. Советская, д. 63, стр. 4; Курган

Pavel A. Nikolaychuk, junior scientist

research laboratory “Advanced materials for industry and biomedicine”

640020; bld. 4, 63, Sovetskaya st.; Kurgan

pavel.nikolaychuk@kgsu.ruВасильевП. А.VasilyevP. A.

Павел Андреевич Васильев, м. н. с.

научно-исследовательская лаборатория «Перспективные материалы для индустрии и биомедицины»

640020; ул. Советская, д. 63, стр. 4; Курган

Pavel A. Vasilyev, junior scientist

research laboratory “Advanced materials for industry and biomedicine”

640020; bld. 4, 63, Sovetskaya st.; Kurgan

ЕноваЮ. А.EnovaYu. A.

Юлия Андреевна Енова, м. н. с.

научно-исследовательская лаборатория «Перспективные материалы для индустрии и биомедицины»

640020; ул. Советская, д. 63, стр. 4; Курган

Yulia A. Enova, junior scientist

research laboratory “Advanced materials for industry and biomedicine”

640020; bld. 4, 63, Sovetskaya st.; Kurgan

Курганский государственный университетРоссияKurgan State UniversityRussian Federation2024160520242912736Copyright © Николайчук П.А., Васильев П.А., Енова Ю.А., 20242024Николайчук П.А., Васильев П.А., Енова Ю.А.Nikolaychuk P.A., Vasilyev P.A., Enova Y.A.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.corrosion-protection.ru/jour/article/view/114

   Рассмотрено использование соединений, экстрагированных из природных источников и отходов пищевой промышленности, в частности, растительного сырья, как перспективного направления поиска ингибиторов коррозии. Изучено ингибирующее влияние отвара из листьев и цветов мелиссы лекарственной Melissa officinalis против коррозии низкоуглеродистой стали Ст3 в среде 0,5 M серной кислоты методами электрохимической поляризации и спектроскопии электрохимического импеданса. Показано, что добавка 100 мг/л экстракта мелиссы лекарственной уменьшает скорость коррозии на 15 %, а добавка 10 г/л – на 75 %. Адсорбция компонентов экстракта на поверхности стали имеет физическую природу, описывается адсорбционной моделью Ленгмюра с хорошим коэффициентом достоверности аппроксимации. Вычисленная энергия Гиббса процесса адсорбции не превышает – 20 кДж/моль. Определенные в работе эффективности ингибирования коррозии низкоуглеродистой стали в среде серной кислоты экстрактом мелиссы лекарственной сравнимы со значениями эффективностей ингибирования коррозии сталей в соляной кислоте. Отвар мелиссы лекарственной показал себя как эффективный и экологичный состав для замедления коррозии сталей в кислых средах.

   The use of compounds extracted from natural sources and waste from the food industry, in particular plant materials, is considered as a promising direction in the search for corrosion inhibitors. The inhibitory ability of the boiling extract from the leaves and the flowers of Melissa officinalis on the corrosion of mild stainless steel EN Fe37-3FN in 0,5 M sulphuric acid medium investigated using electrochemical methods and EIS. It was shown that the addition of 100 mg/L of the Melissa officinalis extract reduces the corrosion rate by 15 %, and that of of 10 g/L – by 75 %. The adsorption of the extract components on a steel surface follows the Langmuir adsorption model, and the nature of adsorption is mostly physical. The adsorption of extract components on the steel surface is described by the Langmuir adsorption model with a good approximation reliability coefficient. The calculated Gibbs energy of the adsorption process does not exceed – 20 kJ/mol, which indicates the physical nature of adsorption. The efficiencies of corrosion inhibition of low-carbon steel in sulfuric acid with lemon balm extract, determined in the work, are comparable to the values of its efficiencies of corrosion inhibition of steels in hydrochloric acid. The Melissa officinalis extract shows itself as perspective and environmentally friendly substance for reducing the steel corrosion rate in acidic environments.

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The authors declare that there are no conflicts of interest present.