corrosionprotectionПрактика противокоррозионной защитыTheory and Practice of Corrosion Protection1998-57382658-6797Association "CARTEC"10.31615/j.corros.prot.2025.115.1-2corrosionprotection-160Research ArticleМАТЕРИАЛЫ И ОБОРУДОВАНИЕ ДЛЯ ПРОТИВОКОРРОЗИОННОЙ ЗАЩИТЫMATERIALS AND EQUIPMENT FOR CORROSION PROTECTIONОценка термического повреждения ткани при использовании электрохирургического инструмента с износостойкими покрытиямиEvaluation of Thermal Tissue Damage Using an Electrosurgical Instrument with Wear-Resistant CoatingsЕвсеевА. К.EvseevA. K.

Евсеев Анатолий Константинович, д.х.н., в.н.с.

129090, г. Москва, Большая Сухаревская площадь, 3, стр. 1

Anatoly K. Evseev, Doctor Sci. in Chemistry, Leading Researcher

bld. 1, 3, B. Sukharevskaya square, Moscow, 129090

evseevak@sklif.mos.ruПоляковН. А.PolyakovN. A.

Поляков Николай Анатольевич, к.х.н., заведующий лабораторией

119071, г. Москва, Ленинский проспект, д. 31, корп. 4

Nikolai A. Polyakov, Cand. Sci. in Chemistry, Head of Laboratory

bld. 4, 31, Leninskiy pr., Moscow, 119071

МягковаИ. Н.MyagkovaI. N.

Мягкова Инна Николаевна, аспирант

125047, г. Москва, Миусская площадь, д. 9

Inna N. Myagkova, Postgraduate

9, Miusskaya square, Moscow, 125047

ГорончаровскаяИ. В.GoroncharovskayaI. V.

Горончаровская Ирина Викторовна, к.х.н., с.н.с.

129090, г. Москва, Большая Сухаревская площадь, 3, стр. 1

Irina V. Goroncharovskaya, Cand. Sci. in Chemistry, Senior Researcher

bld. 1, 3, B. Sukharevskaya square, Moscow, 129090

КирсановИ. И.KirsanovI. I.

Кирсанов Илья Игоревич, к.м.н., заведующий отделением

129090, г. Москва, Большая Сухаревская площадь, 3, стр. 1

Iliya I. Kirsanov, Cand. Sci. in Medicine, Head of Department

bld. 1, 3, B. Sukharevskaya square, Moscow, 129090

ДровосековА. Б.DrovosekovА. B.

Дровосеков Андрей Борисович, к.х.н., с.н.с.

119071, г. Москва, Ленинский проспект, д. 31, корп. 4

Andrey B. Drovosekov, Cand. Sci. in Chemistry, Senior Researcher

bld. 4, 31, Leninskiy pr., Moscow, 119071

КаниболоцкийА. А.KanibolotskiyA. A.

Каниболоцкий Александр Алексеевич, к.м.н., заведующий отделением

129090, г. Москва, Большая Сухаревская площадь, 3, стр. 1

Alexander A. Kanibolotskiy, Cand. Sci. in Medicine, Head of Department

bld. 1, 3, B. Sukharevskaya square, Moscow, 129090

СапринА. А.SaprinA. A.

Саприн Артем Анатольевич, заместитель главного врача по медицинской части

129090, г. Москва, Большая Сухаревская площадь, 3, стр. 1

Artem A. Saprin, Deputy Chief Physician for Medical Affairs

bld. 1, 3, B. Sukharevskaya square, Moscow, 129090

Научно-исследовательский институт скорой помощи имени Н.В. Склифосовского Департамента здравоохранения города МосквыРоссияSklifosovsky Research Institute for Emergency MedicineRussian FederationИнститут физической химии и электрохимии имени А.Н. Фрумкина РАНРоссияFrumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of SciencesRussian FederationРоссийский химико-технологический университет имени Д.И. МенделееваРоссияDmitry Mendeleev University of Chemical Тесhnоlоgy of RussiaRussian Federation2025170720253012129Copyright © Евсеев А.К., Поляков Н.А., Мягкова И.Н., Горончаровская И.В., Кирсанов И.И., Дровосеков А.Б., Каниболоцкий А.А., Саприн А.А., 20252025Евсеев А.К., Поляков Н.А., Мягкова И.Н., Горончаровская И.В., Кирсанов И.И., Дровосеков А.Б., Каниболоцкий А.А., Саприн А.А.Evseev A.K., Polyakov N.A., Myagkova I.N., Goroncharovskaya I.V., Kirsanov I.I., Drovosekov А.B., Kanibolotskiy A.A., Saprin A.A.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.corrosion-protection.ru/jour/article/view/160

В качестве функциональных покрытий электрохирургического инструмента исследованы покрытия Cr-наноалмаз, WC, а также сплавы Ni-P и Ni-W-P. В модельных экспериментах было показано, что использование покрытий Ni-P (15,6 ат.% Р) и Ni-W-P (1,4 ат.% W; 12,6 ат.% Р) приводило к снижению глубины термического поражения по сравнению с непокрытым инструментом. Было предположено, что функциональные свойства покрытий зависят от сочетания многих факторов, в том числе микротвердости, шероховатости, электропроводности, однако вклад того или иного фактора требует более тщательного изучения.

Cr-nanodiamond, WC, and Ni-P and Ni-W-P alloys were studied as functional coatings for electrosurgical instruments. Model experiments showed that the use of Ni-P (15.6 at.% P) and Ni-W-P (1.4 at.% W; 12.6 at.% P) coatings resulted in a decrease in the depth of thermal damage compared to an uncoated instrument. It was suggested that the functional properties of the coatings depend on a combination of many factors, including microhardness, roughness, and electrical conductivity; however, the contribution of any given factor requires more detailed study.

электрохирургиясплав Ni-Pсплав Ni-W-PCr-наноалмазWCelectrosurgeryNi-P alloyNi-W-P alloyCr-nanodiamondWCReferencesMassarweh N.N., Cosgriff N., Slakey D.P. Electrosurgery: History, Principles, and Current and Future Uses // Journal of the American College of Surgeons. – 2006. − V. 202, № 3, − P. 520-530. https://doi.10.1016/j.jamcollsurg.2005.11.017Massarweh, N. N., Cosgriff, N. & Slakey, D. P. (2006). Electrosurgery: History, Prin0ciples, and Current and Future Uses. Journal of the American College of Surgeons, 202(3), 520-530. https://doi.10.1016/j.jamcollsurg.2005.11.017Palanker D., Vankov A., Jayaraman P. On mechanisms of interaction in electrosurgery // New Journal of Physics. − 2008. – V. 10. Article ID 123022. https://doi.10.1088/1367-2630/10/12/123022Palanker, D., Vankov, A. & Jayaraman, P. (2008). On mechanisms of interaction in electrosurgery. New Journal of Physics, 10. Article ID 123022. https://doi.10.1088/1367-2630/10/12/123022Zheng L., Wan J., Long Y., Fu H., Zheng J., Zhou Z. Effect of high-frequency electric distributions on the tissue sticking of minimally invasive electrosurgical devices // Royal Society open science. − 2018. – V. 5, № 7. − Article ID 180125. https://doi.10.1098/rsos.180125Zheng, L., Wan, J., Long, Y., Fu, H., Zheng, J. & Zhou, Z. (2018). Effect of high-frequency electric distributions on the tissue stickning of minimally invasive electrosurgical devices. Royal Society open science, 5(7). Article ID 180125. https://doi.10.1098/rsos.180125Cruz R.L., Nascimento C.D., Souza E.G., Aguzzoli C., Moraes A.C.B.K., Lund R.G. On the Adhesion of Protein in Nitrided Metallic Coatings for Electrosurgical Electrodes of Stainless Steel // Materials Research. − 2022. − № 25. − Article ID e20210547. https://doi.org/10.1557/JMR.1997.0410Cruz, R. L., Nascimento, C. D., Souza, E. G., Aguzzoli, C., Moraes, A. C. B. K. & Lund, R. G. (2022). On the Adhesion of Protein in Nitrided Metallic Coatings for Electrosurgical Electrodes of Stainless Steel. Materials Research, (25). Article ID e20210547. https://doi.org/10.1557/JMR.1997.0410Мягкова И.Н., Евсеев А.К., Поляков Н.А., Дровосеков А.Б., Горончаровская И.В., Шабанов А.К. Физико-химические подходы к улучшению характеристик электрохирургического инструмента // Известия высших учебных заведений. Химия и химическая технология. – 2022. – Т. 65, № 10. – С. 6-13. https://doi.10.6060/ivkkt.20226510.6649Myagkova, I. N., Evseev, A. K., Polyakov, N. A., Drovosekov, A. B., Goroncharovskaya, I. V. & Shabanov, A. K. (2022). Physico-chemical approaches to improve the characteristics of electrosurgical instruments. ChemChemTech, 65(10), 6-13. https://doi.10.6060/ivkkt.20226510.6649 (in Russ.)Lo J.L., Shieu F.S., Hung C.C. Characterization of textured Cr2O3 layer formed on AISI440A stainless steel via anisotropic electropolishing for electrosurgical instruments. // Material Research Express. − 2019. – V. 6. − Article 025402. https://doi.10.1088/2053-1591/aaec5eLo, J. L., Shieu, F. S. & Hung, C. C. (2019). Characterization of textured Cr2O3 layer formed on AISI440A stainless steel via anisotropic elecetropolishing for electrosurgical instruments. Material Research Express, 6. Article 025402. https://doi.10.1088/2053-1591/aaec5eHsu Y.L., Lee C.H., Chiu S.M., Sung Y.C., Yang K.Y., Chu C.W. Anti-sticking PropKerties of PVD CrWNx, CrOx and ZrOx Coatings on Medical Electrode Application // Defect and Diffusion Forum. − 2010. – V. 297, № 301. – Р. 656-663. https://doi.10.4028/www.scientific.net/DDF.297-301.656Hsu, Y. L., Lee, C. H., Chiu, S. M., Sung, Y. C., Yang, K. Y. & Chu, C. W. (2010). Anti-sticking Properties of PVD CrWNx, CrOx and ZrOx Coatings on Medical Electrode Application. Defect and Diffusion Forum, 297(301), 656-663. https://doi.10.4028/www.scientific.net/DDF.297-301.656Han Z., Fu J., Feng X., Niu S., Zhang J., Ren L. Bionic anti-adhesive electrode coupled with maize leaf microstructures and TiO2 coating // RSC Advances. − 2017. − V. 7, № 72. – P. 45287-45293. https://doi.10.1039/C7RA08184GHan, Z., Fu, J., Feng, X., Niu, S., Zhang, J. & Ren, L. (2017). Bionic anti-adhesive electrode coupled with maize leaf microstructures and TiO2 coating. RSC Advances, 7(72), 45287-45293. https://doi.10.1039/C7RA08184GOu K.L., Chu J.C., Hosseinkhani H., Chiou J.F., Yu C.H. Biomedical nanostructured coating for minimally invasive surgery devices applications: characterization, cell cytotoxicity evaluation and an animal study in rat // Surgical Endoscopy. − 2014. – V. 28, № 7. – Р. 21742188. https://doi.10.1007/s00464-014-3450-9Ou K. L., Chu J. C., Hosseinkhani H., Chiou J. F. & Yu C. H. (2014). Biomedical nanostructured coating for minimally invasive surgery devices applications: characterization, cell cytotoxicity evaluation and an animal study in rat. Surgical Endoscopy, 28(7), 2174-2188. https://doi.10.1007/s00464-014-3450-9Konesky G. Porosity Evolution in Electrosurgical Blade Coatings. // MRS Online Proceedings Library. − 1998. – V. 550. – P. 249-254. https://doi.10.1557/PROC-550-249Konesky, G. (1998). Porosity Evolution in Electrosurgical Blade Coatings. MRS Online Proceedings Library, 550, 249-254. https://doi.10.1557/PROC-550-249Shen Y.D., Lin L.H., Chiang H.J., Ou K.L., Cheng H.Y. Research of electrosurgical unit with novel antiadhesion composite thin film for tumor ablation: Microstructural characterisMtics, thermal conduction properties, and biologgical behaviors // Journal of biomedical materials research. Part B, Applied biomaterials. − 2016. – V. 104, № 1. – Р. 96-105. https://doi.10.1002/jbm.b.33363Shen, Y. D., Lin, L. H., Chiang, H. J., Ou, K. L. & Cheng, H. Y. (2016). Research of electrosurgical unit with novel antiadhesion composite thin film for tumor ablation: Microstructural characteristics, thermal conduction properties, and biological behaviors. Journal of biomedical materials research. Part B, Applied biomaterials, 104(1), 96-105. https://doi.10.1002/jbm.b.33363Винокуров Е.Г., Бурухина Т.Ф., Скопинцев В.Д., Васильев В.В., Графушин Р.В. Обзор и анализ разработок и исследований трибологических характеристик покрытий Ni–P как альтернатива хромовым покрытиям // Гальванотехника и обработка поверхности. – 2023. – Т. 31, № 1. – С.19-35. https://doi.10.47188/0869-53262023_31_1_19Vinokurov, E. G., Burukhina, T. F., Skopintsev, V. D., Vasiliev, V. V. & Grafushin, R. V. (2023). Review and analysis of developments and studies of tribological characteristics of Ni–P coatings as an alternative to chromium coatings. Galvanotechnics and surface treatment, 31(1), 19-35. https://doi.10.47188/0869-53262023_31_1_19 (in Russ.)Polyakov N.A. Formation of chromium composite electrochemical coatings from sulfate oxalate solutions based on Cr(III) // Russian Journal of Electrochemistry. – 2016. – V. 52, № 9. – Р. 858-872. https://doi.10.1134/S1023193516090081Polyakov, N. A. (2016). Formation of chromium composite electrochemical coatings from sulfate oxalate solutions based on Cr(III). Russian Journal of Electrochemistry, 52(9), 858-872. https://doi.10.1134/S1023193516090081Дровосеков А.Б. Сравнение коррозионно-защитных свойств химикокаталитических покрытий Ni-P и Ni-W-P // Практика Противокоррозионной Защиты. – 2020. – Т. 25, № 2. – С. 66-71. https://doi.10.31615/j.corros.prot.2020.96.2-8Drovosekov, A. B. (2020). Comparison of corrosion-protective properties of chemical-catalytic coatings Ni-P and Ni-W-P. Practice of Anti-Corrosion Protection, 25(2), 66-71. https://doi.10.31615/j.corros.prot.2020.96.2-8 (in Russ.)Dushik V.V., Ruban E.A., Shaporenkov A.A., Drovosekov A.B., Rozhanskii N.V., Gladkikh N.A. Mechanical Properties and Corrosion–Electrochemical Behavior of Multilayer Coatings of the Ni–P and W–C System Ob-n tained by the Electroless Plating Method and Chemical Vapor Deposition. Part 1. Structure and Mechanical Properties of Coatings // Protection of Metals and Physical Chemistry of Surfacesи. − 2022. – V. 58, № 7. – Р. 1301-1306. https://doi.10.1134/S207020512207004Dushik, V. V., Ruban, E. A., Shaporenkov, A. A., Drovosekov, A. B., Rozhanskii, N. V. & Gladkikh, N. A. (2022). Mechanical Properties and Corrosion-Electrochemical Behavior of Multilayer Coatings of the Ni-P and W-C System Obtained by the Electroless Plating Method and Chemical Vapor Deposition. Part 1. Structure and Mechanical Properties of Coatings. Protection of Metals and Physical Chemistry of Surfaces, 58(7), 1301-1306. https://doi.10.1134/S207020512207004Dushik V.V., Ruban E.A., Drovosekov A.B., Shaporenkov A.A., Rozhanskiy N.V. Synergetic Effect in Ni–P–W and W–C Multilayer Coating Systems Obtained by Chemical-Catalytic Metallization and Chemical-Vapor Deposition // Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques − 2023. – V. 17. − P. 1367-1371. https://doi.10.1134/S1027451023060265Dushik, V. V., Ruban, E. A., Drovosekov, A. B., Shaporenkov, A. A. & Rozhanskiy, N. V. (2023). Synergetic Effect in Ni-P-W and W-C Multilayer Coating Systems Obtained by Chemical-Catalytic Metallization and Chemical-Vapor Deposition. Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques, 17, 1367-1371. https://doi.10.1134/S1027451023060265Taylor K.A. Ancillary properties of vapor-deposited carbide coatings // Thin Solid Films. − 1977. – V. 40. – P. 201-209. https://doi.10.1016/0040-6090(77)90119-5Taylor, K. A. (1977). Ancillary properties of vapor-deposited carbide coatings. Thin Solid Films, 40, 201-209. https://doi.10.1016/0040-6090(77)90119-5Jensen J.A.D., Møller P., Bruton T., Mason N., Russell R., Hadley J., Verhoeven P., Matthewson A. Electrochemical Deposition of Buried Contacts in High-Efficiency Crystalline Silicon Photovoltaic Cells // Journal of The Electrochemical Society. − 2003. – V. 150, № 1. − G49-G57. https://doi.10.1149/1.1528943Jensen, J. A. D., Møller, P., Bruton, T., Mason, N., Russell, R., Hadley, J., Verhoeven, P., & Matthewson, A. (2003). Electrochemical Deposition of Buried Contacts in High-Efficiency Crystalline Silicon Photovoltaic Cells. Journal of The Electrochemical Society, 150(1), G49-G57. https://doi.10.1149/1.1528943Weil R., Parker K. The Properties of Electroless Nickel // In: Electroless Plating: Fundamentals and Applications (Eds. Mallory G.O., Hajdu J.B.). − NY: William Andrew, 1990. – Р. 111-137.Weil, R., Parker, K. (1990). The Properties of Electroless Nickel/ In: Electroless Plating: Fundamentals and Applications (Eds. Mallory G.O., Hajdu J.B.). NY: William Andrew, 111-137.Palaniappa M., Seshadri S.K. Friction and wear behavior of electroless Ni–P and Ni–W–P alloy coatings // Wear. – 2008. – V. 265. − P. 735-740. https://doi.10.1016/j.wear.2008.01.002Palaniappa, M., Seshadri S.K. (2008). Friction and wear behavior of electroless Ni-P and Ni-W-P alloy coatings. Wear, 265, 735740. https://doi.10.1016/j.wear.2008.01.002

The authors declare that there are no conflicts of interest present.