Physical Modeling of the Adsorption Process During Corrosion in oil Pipelines

Abstract

The article discusses the factors influencing the mechanism of the adsorption process during corrosion of oil pipelines. Thus, the article considers the influence of the surface area and volume of particles, their dispersion on the adsorption process during corrosion of oil pipelines, the change in the radius of atoms and molecules depending on the volume and surface area of particles, as well as their number in a particle, the stress per unit surface on which adsorption occurs, from the point of view of forces interaction between the adsorbate and the adsorbent, the internal energy on the surface, the Gibbs energy, the change in entropy, the differences in homogeneous and heterogeneous systems, the influence of surface pressure and osmotic pressure, the volume of adsorption layers, the molecular concentration of a substance on the surface, the twodimensional attraction coefficient, the repulsion coefficient, the Henry equilibrium constant, issues of equilibrium pressure, the degree of filling of the surface, the dependence of the mechanism of interaction of two surfaces on pressure, the influence of the chemical potential of the adsorbed substance, the integral equality of heat during adsorption, the influence of surface energy and free energy on adhesion, and also considers the influence of the standard chemical potential on the adsorption process.