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Development of the Process of Electrodeposition of High-Energy Composite Electrochemical Ni-B and Ni-Al Coatings from Electrolytes Based on Deep Eutectic Solvents. Part 1: Ni-B Composites
https://doi.org/10.31615/j.corros.prot.2025.117.3-5
Abstract
The influence of the composition of electrolytes on the content of boron and aluminum in composite electrochemical coatings Ni-B, respectively, as promising high-energy materials, has been studied. The highenergy properties of Ni-B coatings are due to the reaction of formation of nickel boride Ni3B during the interaction of nickel and boron with the release of a large amount of thermal energy. The optimal ratio of the components in the Ni-B composite is 75 %at. nickel to 25 %at. boron. It can be concluded that the electrolyte based on the deep eutectic solvent mixture of choline chloride ethylene glycol is highly effective in obtaining high-energy composites Ni-B. The use of this electrolyte allows for obtaining the optimal ratio of nickel and boron, and, consequently, the greatest completeness of the reaction when using this CEP as high-energy coatings.
Keywords
Supporting agencies: The work was carried out with the financial support of the Ministry of Science and Higher Education of the Russian Federation.
About the Authors
S. S. Adilova
Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences (IPCE RAS)
Russian Federation
Russian Federation
Sabina S. Adilova, postgraduate student, engineer 2 cat.
bld. 4, 31, Leninskiy pr., Moscow, 119071
A. B. Drovosekov
Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences (IPCE RAS)
Russian Federation
Russian Federation
Andrey B. Drovosekov, Cand. Sci. in Chemistry, senior scientist
bld. 4, 31, Leninskiy pr., Moscow, 119071
N. A. Polyakov
Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences (IPCE RAS)
Russian Federation
Russian Federation
Nikolay A. Polyakov, Cand. Sci. in Chemistry, Head of Laboratory
bld. 4, 31, Leninskiy pr., Moscow, 119071
A. I. Malkin
Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences (IPCE RAS)
Russian Federation
Russian Federation
Alexander I. Malkin, Dr. Sci. in Physics and Mathematics, Head of Laboratory
bld. 4, 31, Leninskiy pr., Moscow, 119071
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Review
For citations:
Adilova S.S., Drovosekov A.B., Polyakov N.A., Malkin A.I. Development of the Process of Electrodeposition of High-Energy Composite Electrochemical Ni-B and Ni-Al Coatings from Electrolytes Based on Deep Eutectic Solvents. Part 1: Ni-B Composites. Theory and Practice of Corrosion Protection. 2025;30(3):52-58. (In Russ.) https://doi.org/10.31615/j.corros.prot.2025.117.3-5
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