Synthesis of alkylamine complexes based on maleic acids and investigation of bactericidal properties
https://doi.org/10.31615/j.corros.prot.2022.103.1-4
Abstract
This article presents the results of research in the field of synthesis of organic complexes based on propyl, butyl, pentyl and hexylamine and maleic acid in a molar ratio of 1:1. The structure and structure of the obtained substances were confirmed by IR and 1H NMR spectroscopy. Some physicochemical properties of the synthesized complex have been determined. In order to study the antimicrobial activity of the complexes obtained, their solutions were prepared in various media (water, isopropyl alcohol and ethyl alcohol) at three different concentrations (2,5; 5; 25 mg/l) and their effect on the vital activity of sulfate-reducing bacteria was studied at a temperature of 30... 32 °C for 15 days. It has been established that at a concentration of 2,5 mg/l, the synthesized complex salts exhibit a 96…98% bactericidal effect, and at a concentration of 5…25 mg/l, they exhibit a 100% bactericidal effect, completely suppressing the vital activity of bacteria. The synthesized complexes exhibit a higher bactericidal effect even at low conc entrations.
Thus, the preparation of organic complexes based on amines and maleic acid, as well as special-purpose inhibitors, components and composite materials based on them, is a very urgent problem. A number of studies have been carried out in this direction
About the Authors
D. B. Agamalieva
Institute of Petrochemical Processes named after Y.H. Mamedaliyev National Academy of Sciences
Azerbaijan
Azerbaijan
Durna Agamaliyeva Babek, Ph.D. in Chemistry, Head of the Laboratory «Corrosion Inhibitors and Preservative Materials»
30, Khojaly Av., Baku
M. M. Abbasov
Institute of Petrochemical Processes named after Y.H. Mamedaliyev National Academy of Sciences
Azerbaijan
Azerbaijan
Vagif Abbasov Maharram, academician, Director
30, Khojaly Av., Baku
V. M. Abbasov
Institute of Petrochemical Processes named after Y.H. Mamedaliyev National Academy of Sciences
Azerbaijan
Azerbaijan
Mutallim Abbasov Maharram, Doctor of Chemical Sciences, Associate Professor
30, Khojaly Av., Baku
Kh. Kh. Alieva
Institute of Petrochemical Processes named after Y.H. Mamedaliyev National Academy of Sciences
Azerbaijan
Azerbaijan
Khanum Aliyeva Khagani, Master
30, Khojaly Av., Baku
References
1. Chongdar, S., Gunasekaran, G., & Kumar, P. (2005). Corrosion inhibition of mild steel by aerobic biofilm. Acta Electrochimica, 50(24), 4655-4665.
2. Zuo, R., Ornek, D., Syrett, B.C., Green, R.M., Hsu, C.-H., Mansfeld, F.B., & Wood, T.K. (2004). Inhibiting mild steel corrosion from sulfate-reducing bacteria using antimicrobialproducing biofilms in Three-Mile-Island process water. Appl. Microbiol. Biotechnol, 64(2), 275- 283. doi: 10.1007/s00253-003-1403-7.
3. Beech, I. B., Sunner, J. (2004). Biocorrosion: towards understanding interactions between biofilms and metals. Curr. Opin. Biotechnol. 15(3), 181-186. doi: 10.1016/j.copbio.2004.05.001.
4. Bermont-Bouis, D., Janvier, M., Grimont, PAD., Dupont, I., & Vallaeys, T. (2007). Both sulfate-reducing bacteria and Enterobacteriaceae take part in marine biocorrosion of carbon steel. Journal of Applied Microbiology, 102(1), 161-168. doi: 10.1111/j.1365-2672.2006.03053x.
5. Kan, J., Chellamuthu, P., Obraztsova, A., Moore, J. E., & Nealson, K.H. (2011). Diverse bacterial groups are associated with corrosive lesions at a Granite Mountain Record Vault (GMRV). Journal of Applied Microbiology, 111(2), 329-337.
6. Videla, H. A., Herrera, L. K. (2007). Biocorrosion in oil recovery systems: Prevention and protection – An update. Edición Especial, 30, 272-279.
7. Abbasov, V. M., Memmedbeyli, E. G., Agamaliyeva, D. B. et al. (2017). Investigation of the bactericidal properties of imidazoline derivatives of synthetic petroleum acids. Oil refining and petro chemistry, (8), 15-18.
8. Ibragimova, M. J., Mammadkhanova, S. A., Abdullazade, A. B., Agamaliyeva, D. B., Seidova, S. A., & Mammadova, N. M. (2020). Influence of oligomethylenaryl sulphonates based on the light gas oil of catalytic cracking on the process of biocorrosion. Theory and Practice of Corrosion Protection, 25(4), 18-25. doi:10.31615/j.corros.prot.2020.98.4-2.
9. Babayeva, V. G., Memmedbeyli, E. G., Agamaliyeva, D. B., et al. (2019). Synthesis of complexes of norborn-5-ene-2-carboxylic acid amide with hexylxhloride and study of its effect to biocorrosion process. Theory and Practice of Corrosion Protection, 24(4), 41-50.
10. Postgate, J. R., Campbell, L. L. (1966). Classification of Desulfovibrio species the non sporulating sulfate-redusing bacteria. Bacteriol. Revs. 30(4), 732-738.
11. Iodometric method for the determination of hydrogen sulfide in water. (1989). OST 39- 234-89.
12.
Review
For citations:
Agamalieva D.B., Abbasov M.M., Abbasov V.M., Alieva Kh.Kh. Synthesis of alkylamine complexes based on maleic acids and investigation of bactericidal properties. Theory and Practice of Corrosion Protection. 2022;27(1):42-48. (In Russ.) https://doi.org/10.31615/j.corros.prot.2022.103.1-4
Views:
221
Email this article 