Study of the selection of effective corrosion inhibitors for various acids
https://doi.org/10.31615/j.corros.prot.2021.102.4-3
Abstract
Corrosion is one of the complications in the acidizing of the bottomhole zone of the well. Corrosion damage can lead to accidents and product loss. One of the most effective ways to protect metal equipment from corrosion is the use of corrosion inhibitors. Cationic surfactants are mainly used because they are capable of forming protective films on the surface of metals. In this work, studies were carried out to determine the effectiveness of industrial corrosion inhibitors in hydrochloric and sulfamic acids in concentrations of 5, 10, 15 (% wt.). As a result, it was found that in hydrochloric acid, corrosion damage is suppressed due to the adsorption of the inhibitor on the metal surface, while in sulfamic acid there are competing processes of adsorption of sulfamate ions and surfactants.
About the Authors
L. F. Davletshina
Russian State University (National Research University) of Oil and Gas named after I.M. Gubkin
Russian Federation
Russian Federation
Luciya F. Davletshina, Ph.D. in Technical Sciences, Associate Professor of the Department of Technology of Chemical Substances for the Oil and Gas Industry
65, Leninsky av., Moscow, 119991
L. I. Tolstyh
Russian State University (National Research University) of Oil and Gas named after I.M. Gubkin
Russian Federation
Russian Federation
Larisa I. Tolstykh, Ph.D. in Chemical Sciences, Associate Professor of the Department of Technology of Chemical Substances for the Oil and Gas Industry
65, Leninsky av., Moscow, 119991
K. A. Poteshkina
Russian State University (National Research University) of Oil and Gas named after I.M. Gubkin
Russian Federation
Russian Federation
Kira A. Poteshkina, Ph.D. in Technical Sciences, Associate Professor of the Department of Technology of Chemical Substances for the Oil and Gas Industry
65, Leninsky av., Moscow, 119991
V. D. Kotekhova
Russian State University (National Research University) of Oil and Gas named after I.M. Gubkin
Russian Federation
Russian Federation
Viktoriia D. Kotekhova, junior scientist branch of the worldclass scientific center «Rational development of the planet’s liquid hydrocarbon reserves»
65, Leninsky av., Moscow, 119991
A. N. Galkina
Russian State University (National Research University) of Oil and Gas named after I.M. Gubkin
Russian Federation
Russian Federation
Alexandra N. Galkina, graduate student of the Department of Technology of Chemical Substances for the Oil and Gas Industry
65, Leninsky av., Moscow, 119991
References
1. Amiyan, V. A., Ugolev, V. S. Method for acidizing wells. A.S. 314883 USSR, MKI E21 B43 / 27; publ. 09/21/71.
2. Silin, M. A., Magadova, L. A., Davletshina, L. F., Davletov, Z. R., & Poteshkina, K. A. (2021). Particularities of sulfamic acid properties increasing the effectiveness of acid treatments (Russian). Neftyanoe khozyaystvo-Oil Industry, (01), 44-47.
3. Silin, M. A., Magadova, L. A. and etc. (2016). Field chemistry. Moscow: Publishing Center of the Russian State University of Oil and Gas (NRU) named after I.M. Gubkin.
4. Mukatdisov, N. I., Farkhutdinova, A. R., & Elpidinsky, A. A. (2014). Corrosion control methods and the benefits of inhibitor protection of oilfield equipment. Bulletin of Kazan Technological University, 17 (3).
5. Gafarov, N. A., Goncharov, A. A., & Kushnarenko, V. M. (1998). Corrosion and protection of equipment in hydrogen sulfide oil fields. Moscow: Nedra.
6. Kuznetsov, Yu. I., Avdeev, Ya. G., & Zel, O. O. Inhibitor of acid corrosion of metals. Patent 2539129 RF C23F 11/04; publ. on 01/10/2015.
7. Fatkullin, R. N., Akhmadeeva, G. I., Minnikhanova, E. A., & Yapryntseva, O. A. (2014). Method for producing acid corrosion inhibitor. Patent 2518829 RF C23F 11/04. Publ. on June 10, 2014.
8. Kravtsov, E. E., Burlak, I. A., Kasyanov, R. O., Fomenko, O. P., Starkova, N. N., Ogorodnikova, N. P., & Kondratenko, A. P. Corrosion inhibitor of metals in sulfuric, hydrochloric and orthophosphoric acids. Patent 2385362 RF C23F 11/04. Publ. on March 27, 2010.
9. Kravtsov, E. E., Vostrikova, D. A., Ismailova, F. G., Gibadullin, R. F., Kitaeva, E. B., Sychev, M. A., & Kondratenko, T. S. (2013). Corrosion inhibitor of metals in sulfuric and hydrolic acids. Patent 2398915 RF C23F 11/04. Publ. on 09/10/2010.
10. Michel, K. Nels, E. Habereder, T. & Keller, A. Corrosion-inhibiting composition for non-ferrous metals // Pat 2483009 RF, IPC S10M141 / 10. No. 2008150626/040. Publ. on May 27, 2013.
11. Silin, M. A., Magadova, L. A., Davletshina, L. F., Pakhomov, M. D., Timerbulatova, Yu. M., & Samsonenko, E. A. (2016). Study of the work of modern corrosion inhibitors in acid systems. Theory and Practice of Corrosion Protection. (4), 22-30.
12. Carbon steel of ordinary quality. Stamps (with Amendment No. 1) (2009). GOST 380- 2005. Moscow: Standartinform.
13. Balezin, S. A. (1976). Why and how metals are destroyed. M.: Education.
14. Amiyan, V. A., Ugolev, V. S., & Kuznetsov, G. N. (1969). Results of research on metal corrosion in sulfamic acid solutions. Oil industry, (10), 62-65.
15. Danilovskaya, L. P., Crimean, R. S. (2017). Metal corrosion inhibitors. Methodical instructions. St. Petersburg: SPbGMTU.
16. Amiyan, V. A. (1970). Physicochemical methods for increasing well productivity. Moscow: Nedra.
17. Glushchenko, V. N. (2010). Oilfield chemistry: Ed. In 5 volumes. V. 4. Acid well treatment. Moscow: Interkontakt Nauka.
18. Khaidarova, G. R. (2014). Corrosion inhibitors for the protection of oilfield equipment. Modern problems of science and education, (6), 286-286.
Review
For citations:
Davletshina L.F., Tolstyh L.I., Poteshkina K.A., Kotekhova V.D., Galkina A.N. Study of the selection of effective corrosion inhibitors for various acids. Theory and Practice of Corrosion Protection. 2021;26(4):32-41. (In Russ.) https://doi.org/10.31615/j.corros.prot.2021.102.4-3
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