Corrosion of downhole equipment in hydrogen sulfur-containing environments
https://doi.org/10.31615/j.corros.prot.2021.100.2-1
Abstract
Complications associated with the corrosive environment, according to JSC Orenburgneft, NK Rosneft for the period 01.01.2021, are among the prevailing ones at oil and gas production facilities and share the 1st place with the scaling factor - 26% of the complicated mechanized well stock. Downhole equipment failures due to corrosion account for 20% of the total number of fixed failures in 2020. By the type of exposure to a corrosive environment at the fields operated within the perimeter of Rosneft, JSC Orenburgneft, hydrogen sulfide and mixed corrosion (caused by simultaneous action of CO2 and H2S) are predominant. The article presents the calculated data on the physicochemical characteristics of aqueous solutions of H2S. The existing approaches for description of the mechanisms of hydrogen sulfide corrosion of oilfield equipment with examples of corrosive destruction at producing string are described A dynamic matrix of the various protection technologies and their applicability in hydrogen sulfide-containing environments is presented, which is used in the fields operated by PJSC NK Rosneft and filled according to the results of laboratory and pilot field tests. The criterions of attribution of equipment to abnormal fund on basis of classification of factors complicated exploitation and following determination of equipment category being used in loc alized norms of NK Rosneft are described
About the Authors
V. E. TkachevaRussian Federation
Valeriya E. Tkacheva, Ph.D. in Technical Sciences, Readership, complication department
bld. 12, Sochinskaya str., Ufa
A. N. Markin
Russian Federation
Andrey N. Markin, Ph.D. in Technical Sciences, Associate Professor at the Dept. of Oilfield Ingineering
2/П, bld. 9, Panel 20, Lenin str., Khanty-Mansi Autonomous territory − Yugra, Nizhnevartovsk
D. V. Kshnyakin
Russian Federation
Dmitrij V. Kshnyakin, Department Manager for work with Mechanized well stock
2, st. Magistralnaya, Buzuluk, Orenburg region
D. I. Mal’cev
Russian Federation
Dmitrij I. Mal’cev, Head of Department in Work with Mechanized well stock
2, st. Magistralnaya, Buzuluk, Orenburg region
V. V. Nosov
Russian Federation
Vasilij V. Nosov, Department Head of Chemization of Industrial Processes
bld. 12, Sochinskaya str., Ufa
References
1. Solov’ev, N. N., Salina, L. S., & Skorobogatov, V. A. (2016). The main regularities of the location and formation of deposits of hydrogen sulfide-containing gas. Lead Gas Science, (1(25)), 125-133.
2. Dean, J. A. (Ed.). (1999). Lange’s handbook of chemistry (Fifteenth ed.). New York: McGraw-Hill.
3. Lurie, Y. Y. (1971). Analytical Chemistry Handbook. Moscow: Chemistry.
4. Vaughan, D. J., & Craig, J. R. (1978). Mineral chemistry of metal sulfides (First ed.). Cambridge: Cambridge University Press.
5. Smith, S. N., & Joosten, M. W. (2006). Corrosion of Carbon Steel by H2S in CO2 Containing Oilfield Environments. Corrosion 2006. NACE International, 06115.
6. Esmaeely, S. N. (2018). Galvanic localized corrosion of mild steel under iron sulfide corrosion product layers (Unpublished doctoral dissertation). Ohio University, May.
7. Sosa, E., Cabrera-Sierra, R., Oropeza, M. T., Hernandez, F., Casillas, N., Tremont, R., Gonzalez, I. (2003). Chemical characterization of corrosion films electrochemically grown on carbon steel in alkaline sour environment. Journal of the Electrochemical Society, (150), B530-B535.
8. Wallaert, E., Depover, T., Graeve, I. D., & Verbeken, K. (2018). FeS Corrosion Products Formation and Hydrogen Uptake in a Sour Environment for Quenched and Tempered Steel. Metals, (8), 62. doi:10.3390/met8010062.
9. Stationary distillation desalination plants. Methods for chemical analysis of salt water and distillate for gas content (1985). GOST 26449.3–85.
10. Standard Test Method for Sulfide Ion in Water. Published date: 05-15-2009. American Society for Testing and Materials (2009). ASTM D 4658–09.
11. Eaton, A. D. (1999). Standard methods for the examination of water and wastewater (20th ed.) (1303086721 958859318 L. S. Clescerl & 1303086722 958859318 A. E. Greenberg, Eds.).
12. Gonik, A. A. (1966). Hydrogen sulfide corrosion and measures to prevent it. Moscow: Nedra.
13. Sinyutina, S. E., & Vigdorovich, V. I. (2002). Current state and problems of hydrogen sulfide corrosion of metals in electrolyte solutions. Vestnik TSU, 7(3), 319-328.
14. Saakiyan, L. S., & Efremov, A. P. (1982). Corrosion protection of oil and gas field equipment. Moscow: Nedra.
15. Novakovsky, V. M. (1980). To the standard scientific system of corrosionelectrochemical concepts and terms. Zashchita metallov, 6(3), 250-264.
16. Markides, A., & Hakerman, N. (1955). Industrial & Engineering Chemistry Research, 47(9), 1773-1781.
17. Iofa, Z. A. (1970). On the effect of hydrogen sulfide on the corrosion of iron and on the adsorption of inhibitors in acidic solutions. Zashchita metallov, 6(5), 491.
18. Tewari, P. H., & Campbell, A. B. (1979). Canadian Journal of Chemistry. Dissolution of Iron during the Initial Corrosion of Carbon Steel in Aqueous H2S Solutions, 57, 188-196.
19. Barinov, O. G. (2002). The mechanism of localization of corrosion on iron in solutions containing hydrogen sulfide (Doctoral dissertation, Scientific Research Physicochemical Institute, 2002) (p. 129). Moscow.
20. Houyi, M., Xiaoliang, C., & Shenhao, C. (1998). Journal of Electroanalytical Chemistry, (451), 11-17.
21. Kolotyrkin, Y. M., & Florianovich, G. M. (1971). Abnormal phenomena during the dissolution of metals. Results of Science. Electrochemistry, 7, 5-64.
22. Gutman, E. M., Nizamov, K. R., Getmansky, M. D., & Nizamov, E. A. (1983). Protection of oilfield equipment from corrosion: A textbook for workers. Moscow: Nedra.
23. Saakiyan, L. S. (1985). Protection of oilfield equipment from corrosion: A worker’s handbook. Moscow: Nedra.
24. Sukhotin, A. M., Chekulaeva, E. I., Knyazheva, V. M., & Zaitsev, V. A. (1987). Corrosion resistance of chemical production equipment: Methods for protecting equipment from corrosion: Reference publication. Leningrad: Chemistry.
25. Shashkova, L. V. (2013). Fractalsynergistic aspects of microdamage, fracture and optimization of the steel structure under conditions of hydrogen brittleness and hydrogen sulfide cracking. Orenburg: Orenburg State University.
26. Petroleum and natural gas industries. Materials for use in H2S-containing environments in oil and gas production. Part 1. General principles for selection of cracking-resistant materials (2011). GOST R 53679-2009.
27. Iofa, Z. A. (1980). On the mechanism of action of hydrogen sulfide and inhibitors on the corrosion of iron in acidic solutions. Zashchita metallov, 16(3), 295-300.
28. Waard, C., & Milliams, D. E. (1975). Carbonic Acid Corrosion of Steel. Corrosion, 31(5), 177-188.
29. Waard, C., & Milliams, D. E. (1975). Carbonic Acid Corrosion of Steel. Corrosion, 31(5), 177-181.
30. Waard, C., & Milliams, D. E. (1975). First International Conference on the Internal and External Protection of Pipes. In (Paper F1 ed.). UK: University of Durham.
31. Waard, C., Lotz, U., & Milliams, D. E. (1991). Predictive Model for CO2 Corrosion Engineering in Wet Natural Gas Pipelines. Corrosion, 47(12), 976-985.
32. Waard, C., & Lotz, U. (1993). Prediction of CO2 Corrosion of Carbon Steel. In Corrosion’93. (Paper 69).
33. Guidelines for the application of anticorrosion measures in the preparation of projects for the development and reconstruction of oil fields (1986). RD 39-0147103-362-86.
34. Gutman, E. M., Getmansky, M. D., Klapchuk, O. V., & Krigman, L. E. (1988). Protection oil fields gas pipelines from hydrogen sulfide corrosion. Moscow: Nedra.
35. Konischev, K. B., Semenov, A. M., Chaban, A. S., Lobanova, N. A., & Kashkovsky, R. V. (2019). Features of stress corrosion cracking mechanism of pipe metal in environments containing hydrogen sulfide and carbon dioxide. Vesti Gazovoy Nauki, (3(40)), 60-66.
36. Zyryanov, A. O., Ioffe, A. V., Tetyueva, T. V., & Vyboyshchik, M. A. (2018). Strength of heterogeneous structures. Peculiarities of corrosion of tubing made of 15Х5МФБЧ steel in environments containing CO2 and H2S. (p. 198). Moscow: Studio-Print LLC.
37. Gonik, A. A. (1976). Corrosion of oilfield equipment and measures to prevent it. Moscow: Nedra.
38. Jones, L. W. (1998). Corrosion and Water Technology for Petroleum Producers. Tulsa: Oil & Gas Consultants International.
39. Zavyalov, V. V. (2005). He operational reliability problems of pipelines at a late stage of field development. Moscow: VNIIOENG.
40. Zorkina, L. M. (Ed.). (1989). Waters of oil and gas fields in USSR: Reference book. Moscow: Nedra.
41. Dolmatova, L. A. (2011). Features of chemical composition the water rivers of closeddrainage region the Ob-Irtysh interfluve. Mir Nauki, Kul’tury, Obrazovaniya, (6(31)), 238-241.
42. Water for flooding oil reservoirs. Quality requirements (1988). OST 39-225-88.
43. Burger, E. D., Jenneman, G. E., Bache, O., Jensen, T. B., & Soerensen, S. (2005). A Mechanistic Model To Evaluate Reservoir Souring in the Ekofisk Field. In SPE International Symposium on Oilfield Chemistry. Texas: The Woodlands. doi:https://doi.org/10.2118/93297-MS.
44. Burger, E. D., & Jenneman, J. E. (2009). Forecasting the Effects of Reservoir Souring From Waterflooding a Formation Containing Siderite. In SPE International Symposium on Oilfield Chemistry (SPE-121432-MS). Texas: The Woodlands. doi:https://doi.org/10.2118/121432-MS
45. Pat. USA № 2017/0116359 A1.
46. Markin, A.N., Sukhoverkhov, S.V., Brikov, A.V. (2016) Oilfield Chemistry: Analytical methods: Yuzhno-Sakhalinsk: Sakhalin Regional Printing House.
47. Vigdorovich, V. I., & Makarov, A. P. (2015). Control of corrosiveness the hydrogen sulfide-containing media and assessment the effectiveness of protection methods during continuous operation of oil and gas production facilities. Theory and Practice of Corrosion Protection, (1(75)), 60-71.
48.
Review
For citations:
Tkacheva V.E., Markin A.N., Kshnyakin D.V., Mal’cev D.I., Nosov V.V. Corrosion of downhole equipment in hydrogen sulfur-containing environments. Theory and Practice of Corrosion Protection. 2021;26(2):7-26. (In Russ.) https://doi.org/10.31615/j.corros.prot.2021.100.2-1