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Theory and Practice of Corrosion Protection

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Hastelloy G 35 сorrosion tests for intergranular corrosion resistance

https://doi.org/10.31615/j.corros.prot.2021.100.2-2

Abstract

The article is devoted to the analysis of corrosion behavior and assessment of the resistance of Hastelloy G 35. Nickel-based alloys (steels) containing chromium, molybdenum, tungsten, possibly iron are widely used as materials for the manufacture of equipment in high-temperature technological processes using solutions of highly hygroscopic halides (chlorides) in molten halides (chlorides) of alkali metals. During the operation of the equipment, the instability of the surface of apparatus and pipelines to corrosion is determined. In this test, 4 samples of 80×20×3 mm were used, of which 2 samples were subjected to provoking heating, and 2 samples were examined in their normal state. Our tests were carried out in a boiling aqueous solution of iron sulfate and sulfuric acid for 48 ± 0.25 h. Further, the bent samples were examined using an MBS-9 microscope with a magnification of х8. The results of corrosion tests are also presented. As a result of the study, the rate of penetration of corrosion of the alloy was calculated. Hastelloy microstructure is presented. The average depth of destruction was determined from the six maximum values detected in six fields of view. According to the research results, the corresponding conclusions were made.

About the Authors

J. F. Gordeeva
Sverdlovsk Research Institute of Chemical Engineering
Russian Federation

Julia F. Gordeeva, research engineer, postgraduate

32, st. Griboedova, Yekaterinburg



E. S. Filatov
The Institute of High Temperature Electrochemistry of the Ural Branch of the Russian Academy of Sciences
Russian Federation

Evgeny S. Filatov, Doctor of Chemistry, senior researcher

20, st. Akademicheskaya, Yekaterinburg



A. S. Derbyshev
Sverdlovsk Research Institute of Chemical Engineering
Russian Federation

Alexander S. Derbyshev, Doctor of Technical Sciences

32, st. Griboedova, Yekaterinburg



V. Ya. Kudyakov
The Institute of High Temperature Electrochemistry of the Ural Branch of the Russian Academy of Sciences
Russian Federation

Vladimir Ya. Kudyakov, Doctor of Chemistry, Professor

20, st. Akademicheskaya, Yekaterinburg



References

1. Stutsa, M. G. (2014). In Zirconium XXI century. Russia, Glazov, 5-10.

2. Karpov, V. V., Bazhenov, A. V. (2015)Corrosion resistance of alloys of Hastelloy in chloroaluminate melts, Chimica Techno Acta, 131-138.

3. Nickel-based alloys. Methods for determination of resistance against intergranular corrosion. (1991). RD 24.200.15-90. Introduction. 1991-04- 01. Moscow: Standards Publishing House, 1991.

4. Smirnov, M. V., Ozerianaya, I. N. (1973). Corrosion of metals and corrosion protection. Results of science and technology. Moscow: VINITI, 2, 171-208.


Review

For citations:


Gordeeva J.F., Filatov E.S., Derbyshev A.S., Kudyakov V.Ya. Hastelloy G 35 сorrosion tests for intergranular corrosion resistance. Theory and Practice of Corrosion Protection. 2021;26(2):27-31. (In Russ.) https://doi.org/10.31615/j.corros.prot.2021.100.2-2

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ISSN 1998-5738 (Print)
ISSN 2658-6797 (Online)