The complexes of synthetic and petroleum acids N-derivatives as steel acidic corrosion inhibitors
https://doi.org/10.31615/j.corros.prot.2020.96.2-2
Abstract
Oxy- and petroleum acids were synthesized by liquid-phase oxidation of naphthen-paraffin concentrate, separated from diesel fraction of Azerbaijani oils mixture with atmospheric oxygen in the presence of heterogeneous catalytic systems. As the catalyst aluminum nano-oxide modified by Cr ,Co, Mn transition metals was used. The oxidation was carried out in reactor of bubble type in the interval of temperature 135…140 ºС during 5 h. Their imidazoline derivatives were obtained by the use of the synthesized acids and polyamines, and the complexes were prepared on the basis of them and aliphatic monobasic acids (formic and acetic) at equal molar ratio. Their influence was studied on the kinetics of the corrosion process of C1018 steel samples in 1% solution of NaCl, saturated by CO2 at 50 °С. The complexes were tested as inhibitors of carbon dioxide corrosion at concentration of 25 and 50 ppm in 20 h. According to obtained data, the usage of different concentrations of complexes decreases corrosion rate and metal loss (up to 9…10 times). The values of surface coverage (θ) and the extent of inhibition efficiency (IE, %) of corrosion process of steel example in CO2-medium in presence of prepared complexes were calculated. IR spectra of surface layer of used electrodes were recorded before and after adding prepared complexes into corrosion medium. As a result of the studies it was determined, that the obtained complexes had high prospects for use (protection degree 97…98%) as CO2-corrosion inhibitors in suppressing of carbon dioxide corrosion of steel equipment
About the Authors
L. I. Aliyeva
Institute of Petrochemical Processes named after Y.H.Mammadaliyev National Academy of Sciences
Azerbaijan
Azerbaijan
Leylufer I. Aliyeva, Doctor of Technical Sciences, Professor, Head of Department
30, Khojaly ave, Az 1025, Baku
L. M. Afandiyeva
Institute of Petrochemical Processes named after Y.H.Mammadaliyev National Academy of Sciences
Azerbaijan
Azerbaijan
Lala M. Efendiyeva, Doctor of Chemistry, assistant Professor, Head of Laboratory
30, Khojaly ave, Az 1025, Baku
V. M. Abbasov
Institute of Petrochemical Processes named after Y.H.Mammadaliyev National Academy of Sciences
Azerbaijan
Azerbaijan
Vagif M. Abbasov, Doctor of Chemistry, Professor, Academician, Director
30, Khojaly ave, Az 1025, Baku
G. Yu. Rustamly
Institute of Petrochemical Processes named after Y.H.Mammadaliyev National Academy of Sciences
Azerbaijan
Azerbaijan
Gulay Y. Rustamli, researcher
30, Khojaly ave, Az 1025, Baku
S. F. Akhmedbekova
Institute of Petrochemical Processes named after Y.H.Mammadaliyev National Academy of Sciences
Russian Federation
Russian Federation
Saida F. Akhmedbekova, Ph.D. in Chemistry, leading
researcher
30, Khojaly ave, Az 1025, Baku
References
1. Nesic, S., Lee, K. L. J. (2003). A Mechanistic Model for CO2 in the presence of protective iron carbonate films – Part 3: The film growth model. Corrosion/2003: NACE International, 59(7), 616-628.
2. Nesic, S., Nordsveen, M., Nyborg, R., & Stangeland, A. (2003). A mechanistic model for carbon dioxide corrosion of mild steel in the presence of protective iron carbonate films – Part 2: A numerical experiment. Corrosion/2003: NACE International, 59(6), 489-497.
3. Moiseeva, L. S. (2005). Carbon dioxide corrosion of oil and gas field equipment. Protection of Metals. 41(1), 76-83.
4. Kuznetsov, Yu. I., Ibatulin K. A. (2002). On the inhibition of the carbon dioxide corrosion of steel by carboxylic acids. Protection of metals, 38 (5), 439-444.
5. Vigdorovich, V. I., Tsigankova, L. E. (2011). Inhibition of hydrogen sulfide and carbon dioxide corrosion of metals. Universalisms of inhibitors. Moscow: CARTEC.
6. Fakhretdinov, P. S., Borisov, D. N., Romanov, G. V., Khodirov, Yu. P., Galiakperov, R. M., & Ziyatdinov, A. Sh. (2008). Corrosion inhibitors from the series of ammonium compounds on the basis of α-olefins. Neftegazovoye delo, 2, 31.
7. Silin, M. A., Magadova, L. A., Davletshina, L. F., Pakhomov, M. D., Timerbulatov, Yu. M., & Samsonenko, E. A. (2016). Study of modern corrosion inhibitor works in acidic systems. Theory and Praсtice of Corrosion Protection, (4), 22-30.
8. Okafor, P. C., Liu, X., & Zheng, Y. G. (2009). Corrosion inhibition of mild steel by ethylamino imidazoline derivative in CO2-saturated solution. Corrosion Science, 51(4), 761-768.
9. Finsgar, M., Jackson, J. (2014). Application of corrosion inhibitors for steels in acidic media for the oil and gas industry: A review. Corrosion Science, 86, 17-41.
10. Shaker, N. O., Badr, E. E., and Kandeel, E. M. (2011). Adsorption and inhibitive properties of fatty imidazoline surfactants on mild steel. Pelagia Research Library Der Chemica Sinica, 2(4), 26-35.
11. Abbasov, V. M., Zeynalov, E. B., Aliyeva, L. I. and et al. (2013). Selective oxidation of naphtheneisoparaffin hydrocarbons of diesel fuel in the presence of Cr- and Mn-salts of natural petroleum acids. Processes of petrochemistry and oil refining, 3 (55), 183-190.
12. Afandiyeva, L. M., Ibragimov, Kh. J., Rustamli, G. Yu., Akhmedbekova, S. F., Mamedova, Kh. R., Aliyev, B. M., & Abbasov, V. M. (2019). Catalytic oxidation of naphthene-paraffin fraction by air oxygen in the presence of γ-Al2O3 modified by salts Cr, Co, Mn. Chemical Problems, 2(17), 323-329.
13. Tolchev, A. V. (2011). Phase and structural transformations of aluminum oxide compounds with varying degrees of dispersion. Bulletin of Chelyabinsk State University, 39(254), 24-29.
14. Rzayeva, N. Sh., Abbasov, V. M., Aliyeva, L. I., & Nasibova, L. I. (2019). Development of effective bactericide and inhibitors of CO2 corrosion. Theory and Practice of Corrosion Protection, 24(2), 52-58.
15. Song, F. M., Kirk, D. W., Graydon, J. W., & Cormack, D. E. (2004). Predicting carbon dioxide corrosion of bare steel under an aqueous boundary layer. Corrosion, 60(8), 736-748.
16. Taleb, H. I., Zour, M. A. (2011). Corrosion inhibition of mild steel using fig leaves extract in hydrochloric acid solution. Int. J. Electrochem. Sci., 6(12), 6442-6455.
17. Abdel-Gaber, A. M, Abd-El-Nabey, B. A, Khamis, E., & Abd-El-Khalek, D. E. (2011). A natural extract as scale and corrosion inhibitor for steel surface in brine solution. Desalination, 278(1), 337-342.
18. Flis, J., Zakroczymski, T. (1996). Impedance study of reinforcing steel in simulated pore solution with tannin. Electrochem. Soc., 143(8), 2458-2464.
19. Szklarska-Smialowska, Z., Mankowski, J. (1978). Crevice corrosion of stainless steels in sodium chloride solution. Corrosion Science, 18(11), 953-960.
Review
For citations:
Aliyeva L.I., Afandiyeva L.M., Abbasov V.M., Rustamly G.Yu., Akhmedbekova S.F. The complexes of synthetic and petroleum acids N-derivatives as steel acidic corrosion inhibitors. Theory and Practice of Corrosion Protection. 2020;25(2):18-25. (In Russ.) https://doi.org/10.31615/j.corros.prot.2020.96.2-2
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