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Corrosion Resistance of Copper-Doped Lead in Sodium Chloride Solution
https://doi.org/10.31615/j.corros.prot.2025.116.2-5
Abstract
Lead is a very ductile metal and is widely used in industry both in its pure form and in the form of alloys with other components. The high resistance of lead against corrosion in many mineral acids has led to its widespread use in the chemical industry for lining chemical equipment, pipelines and containers, for hot leading instead of tinning. Lead is resistant to corrosion because a film of hydroxide forms on its surface upon contact with air and a film of lead sulfate upon contact with sulfuric acid.
This paper presents the results of a study of the electrochemical corrosion of lead-copper alloys in an electrolyte medium of 0.03, 0.3 and 3.0% NaCl. Corrosion and electrochemical studies of the alloys were carried out by the potentiostatic method on a PI-50-1.1 potentiostat in a potentiodynamic mode at a potential sweep rate of 2 mV/s. It has been shown that alloying lead with copper increases its corrosion resistance by 15…20%. The main electrochemical potentials of free corrosion, pitting formation and repassivation of the lead corrosion process during copper alloying shift to a positive range of values, and decrease from the concentration of sodium chloride.
About the Authors
S. U. Khudoiberdizoda
V.I. Nikitin Chemistry Institute of the National Academy of Sciences of Tajikistan
Tajikistan
Tajikistan
Saidmiri U. Khudoiberdizoda, Cand. in Technical Sciences, Leading Researcher
299/2, Sadriddin Aini st., Dushanbe, 734063
I. N. Ganiev
V.I. Nikitin Chemistry Institute of the National Academy of Sciences of Tajikistan
Tajikistan
Tajikistan
Izatullo N. Ganiev, Academician of the National Academy of Sciences of Tajikistan, Doctor of Chemical Sciences, Professor, Head of the Laboratory
299/2, Sadriddin Aini st., Dushanbe, 734063
J. H. Dzhayloev
V.I. Nikitin Chemistry Institute of the National Academy of Sciences of Tajikistan
Tajikistan
Tajikistan
Jamshed H. Dzhayloev, Cand. in Technical Sciences, Leading Researcher
299/2, Sadriddin Aini st., Dushanbe, 734063
S. Yu. Kireev
Penza State University
Russian Federation
Russian Federation
Sergey Yu. Kireev, Doctor of Technical Sciences, Professor
40, Krasnaya str., Penza, 440026
A. Z. Yangurazova
Penza State University
Russian Federation
Russian Federation
Alfiya Z. Yangurazova, Senior Lecturer
40, Krasnaya str., Penza, 440026
Yu. N. Kirilina
Penza State University
Russian Federation
Russian Federation
Yulia N. Kirilina, Cand. in Technical Sciences, Associate Professor
40, Krasnaya str., Penza, 440026
N. N. Mullaeva
Center for Research of Innovative Technologies of the National
Academy of Sciences of Tajikistan
Tajikistan
Tajikistan
Nukra N. Mullaeva, Cand. in Technical Sciences, Leading Researcher
References
1. Sriram H., Jagadeeswaran I. (2022). EU 2015/863: Restriction of Hazardous Substanc5es (RoHS)-3. Medical Device Guidelines and Regulations Handbook. Cham.: Springer International Publishing, 297-307.
2. Torretta V. et al. (2013). Management of waste electrical and electronic equipment in two EU countries: A comparison. Waste Man agement, 33(1), 117-122.
3. Ghisellini P., Passaro R., Ulgiati S. (2023). Environmental and social life cycle assessment of waste electrical and electronic equipment management in Italy according to EU directives. Environments, 10(7), 106.
4. Joscha B., Annkatrin K., Michael R. (2024). Beyond RoHS and REACH: Relevant CMR Substances in Electronic Products. Electronics Goes Green 2024+(EGG). IEEE, 1-5.
5. Stolyarenko, V. A., Tabeleva, N. N. (2022). Requirements of the technical regulations of the Eurasian Economic Union «On the safety of chemical products» (TR EAEU 041/2017). Prospects for implementation in the Republic of Belarus. Hygiene, ecology and health risks in modern conditions, 208-210. (in Russ.)
6. Ruusila, V. et al. (2013). The effect of microstructure and lead content on the tribological properties of bearing alloys. Proceedings of the Institution of Mechanical Engineers, Part J: Journal of Engineering Tribology, 227(8), 878-887.
7. Rudychev, V. G. et al. (2023). Optimization of radiation shields made of Fe and Pb for the spent nuclear fuel transport casks. Nuclear Engineering and Technology, 55(2), 690-695.
8. Mallikarjun, S., Shruthi, A. A (2022). Study on Dynamic Response of High-Rise Buildings using Lead Rubber Bearing Isolator. CVR Journal of Science and Technology, 23(1), 14-20.
9. Akkurt, İ. et al. (2012). Determination of some heavyweight aggregate half value layer thickness used for radiation shielding. Acta Physica Polonica A, 121(1), 138-140.
10. Arif Sazali M., Alang Md Rashid N. K., Hamzah K. (2019). A review on multilayer radiation shielding. IOP Conference Series: Materials Science and Engineering. IOP Publishing, 555(1), 012008.
11. Hu G. et al. (2020). Study on the design and experimental verification of multilayer radiation shield against mixed neutrons and γ-rays. Nuclear Engineering and Technology, 52(1), 178-184.
12. Mayco international: official site. URL: https://maycointernational.com/blog/what-arecars-made-of/ (accessed 09.01.2025).
13. Bryantseva, V. I., Tskhe, L. A., Bunzhe, V. G., Dunaev, Yu. D. & Kiryakov, G. Z. (1969). Elekrokhimiya metallov and amalgam. Alma-ata: Nauka KazSSR, 23-28. (in Russ.)
14. Dunaev, Yu. D., Bryantseva, V. I., Lukin, E. G. & Bunje, V. G. (1972). Elekrokhimicheskie issledovanie amalgamnikh system. Alma-ata: Nauka KazSSR. (in Russ.)
15. Mullaeva, N. M., Ganiev, I. N. (2015). Splavi svinsa s shelochnozemelnimi metallami. Monografiya. Dushanbe: Andaleb. (in Russ.)
16. Ganiev, I. N., Saidova, F. R., Khudoiberdizoda, S. U. & Dzhailoev, D. H. (2024). Anodnoe povedenie alyuminievogo splava АlMg5,5Li2,1Zr0,15 tipa dyuralyumin so strongsiem v srede vodnogo rastvora NaCl. Galvanotekhnika I obrabotka poverkhnosti, 32(1-2), 13-19. (in Russ.)
17. Khudoyberdizoda, S. U., Ganeev, I. N., Mullaeva, N. M., Jalaev, J. H. & Yakubov, U. Sh. Potensiodinamicheskie iccledovanie splavov svinsa s tellurom, v srede elektrolita NaCl. Vest-v nik Tadjikskogo natsionalnogo universiteta. Seriya estestvennikh nauk, (2), 238-245. (in Russ.)
18. Khudoyberdizoda, S. U., Ganeev, I. N., Mulaeva, N. M., Jalaev, J. H. & Yakubov, U. Sh. (2019). Potensiodinamicheskie iccledovanie svinsovogo svlava SSu3, legirovannogo medyu v srede elektrolita NaCl. Vestnik Tadjikeskogo natsionalnogo universiteta. Seriya est-e estvennikh nauk, (1), 206-213. (in Russ.)
19. Kireev, S. Yu., Sinenkova, S. R., Kireeva, S. N., Naumov, L. V., Kozlov, G. V. & Balyberdin, A. S. (2024). Poluchenie I svoystva kompozitsiononikh elekrokhimicheskikh pokritiy indiy-grafit I nikel-karbid volframa. Galvanotekhnika I obrabotka poverkhnosti, 32(1-2), 6-12. (in Russ.)
20. Niezov, O. Kh., Ganiev, I. N., Mulloeva, N. M. & Khudoiberdizoda, S. U. (2018). Potensiodinamicheskie iccledovanie svlava SSu3, legirovannogo kalsiem v srede elektrolita NaCl. Vestnik Sibirskogo gosudarstvennogo industrisalnogo universiteta, (1), 37-41. (in Russ.)
Review
For citations:
Khudoiberdizoda S.U., Ganiev I.N., Dzhayloev J.H., Kireev S.Yu., Yangurazova A.Z., Kirilina Yu.N., Mullaeva N.N. Corrosion Resistance of Copper-Doped Lead in Sodium Chloride Solution. Theory and Practice of Corrosion Protection. 2025;30(2):56-63. (In Russ.) https://doi.org/10.31615/j.corros.prot.2025.116.2-5
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