Product-based preservation liquids nitration of alkenes
https://doi.org/10.31615/j.corros.prot.2022.104.2-2
Abstract
The article presents the results of nitration reactions of α-olefins in a mixture of orthophosphoric and nitric acids. The results of carrying out the reaction under various reaction conditions are presented. The results of analyzes of the obtained nitro compounds based on the structure of decene-1 nitro derivatives are shown. Also, the results of tests obtained for nitro compounds as inhibitory components in the mineral oil I-40 in various aggressive environments, namely in a hydrochamber, in a 0,001% solution of H2SO4, in sea water, as well as test results for the quality of conservation liquids of the mixture are given obtained unsaturated nitro compounds with monoethanolamide. under the same conditions.
About the Authors
L. A. Makhmudova
Azerbaijan State University of Oil and Industry Department
Azerbaijan
Azerbaijan
Leyla A. Makhmudova, Ph.D. in Chemistry, assistant professor
16/21, Azadlig Avenue, Baku
E. Z. Kuliyev
Azerbaijan State University of Oil and Industry Department
Azerbaijan
Azerbaijan
Eltun Z. Kuliyev, gradient student
16/21, Azadlig Avenue, Baku
References
1. Bendall, K. C. (1995) Corrosion resistant alloys – an industry-wide overview of applications”. Anti-Corrosion Methods and Materials, 42(2), 12-15. https://doi.org/10.1108/eb007356.
2. Chelyabieva, V. N., Smykun, N. V., & Kurmakova, I. N. (2003). Inhibitory and biocidal activity of imidazo[1,2-A]azepinium bromides. Protection of metals, 39(4), 395-398.
3. Abbasov, V. M., Hasanov, Е. К., Karimova, N. Q. (2005). Processes of petrochemistry and oil refining, 1(2), 15.
4. Abramzon, А. А. Zaychenko, L. P., & Fraynhold, S. I. (1988). Surfactants. Leningrad: Chemistry.
5. Abbasov, V. M., Karimova, N. Q., & Hasanov, E. K. (2003). Processes of petrochemistry and oil refining, 2(13), 14.
6. Stepanov, A. V., Veselovsky, V. V. (2003). Reactions of olefins with nitrogen oxides and other nitrosating and nitrating reagents. Russian Chemistry, 72(4), 395-398. doi: org/10.1070/RC2003v072n04ABEH000769.
7. Rasulov, S. R., Makhmudova, L. A. (2012). Study of O- and N-containing derivatives of α-olefins as oil-soluble corrosion inhibitors. Proceedings of the Russian State University of Oil and Gas named after I.M. Gubki, 267(2), 140-148.
8. Isozaki, S., Nishiwaki P., Chem. Com. (2001), 15. 1352. doi: 10.1134/S0028242119020102.
9. Makhmudova, L. A. (2018). Study of the protective effect of nitro-nitroso adducts against microbiological corrosion. Theory and Practice of Corrosion Protection, 87(1), 51-53.
10. Talybov, A. G., Badalova, G. N., Mursalov, N. I., & Makhmudova, L. A. (2018). Investigation of dihydropyridine derivatives as inhibitors of CO2 - and H2S-corrosion. Corrosion: materials, protection, (11), 28-32.
11. Mahmudova, L. А. (2019). Optimization of regime parameters of the nitration reaction of long-chain linear α-olefins in polar and nonpolar solvents. Petrochemicals, 59(2), 166- 171. doi: 10.1134/S0028242119020102.
Review
For citations:
Makhmudova L.A., Kuliyev E.Z. Product-based preservation liquids nitration of alkenes. Theory and Practice of Corrosion Protection. 2022;27(2):26-32. (In Russ.) https://doi.org/10.31615/j.corros.prot.2022.104.2-2
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