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Influence of oligomethylenaryl sulphonates based on the light gas oil of catalytic cracking on the process of biocorrosion

https://doi.org/10.31615/j.corros.prot.2020.98.4-2

Abstract

This article presents the results of studies in the field of synthesis of water-soluble salts of oligomethylene aryl sulfonates synthesized using aromatic hydrocarbons contained in the gas oil fraction of the catalytic cracking process of oil as raw materials. Based on the synthesized various salts of oligoaromatic sulfonic acids (sodium, potassium, ammonium salts), solutions of various concentrations (35; 75; 150; 200 mg/l) were prepared and their effect on the vital activity of sulfate-reducing bacteria at a temperature of 30…32 °С for 7…14 days was studied. It was found that complex salts synthesized on the basis of oligomeric sulfonic acids of aromatic hydrocarbons of the gas oil fraction (N-1, N-2, N-3) at a concentration of 150 mg/l exhibit more than 90%, and at a concentration of 200 mg/l, 100% bactericidal effect and completely inhibits the growth of bacteria. It was revealed that the synthesized salts of sulfonic acids exhibit a relatively higher antimicrobial activity against SRB than the industrial bactericidal inhibitors AMDOR-IK-7 and AMDOR-IK-10 taken as a reference. Based on the studies, it was found that the synthesized salts of oligosulfonic acids completely inhibit the growth of sulfate-reducing bacteria at much lower concentrations compared to the industrially used bactericidal inhibitors taken as a reference. In particular, at a concentration of 150 mg/l, the bactericidal effect is more than 90% against 75…80% for the standard.

About the Authors

M. J. Ibragimova
Institute of Petrochemical Processes named after Y.H. Mamedaliyev National Academy of Sciences
Azerbaijan

Minaver J. Ibragimova, doctor of chemical sciences, professor, head of the Laboratory «Polyfunctional Monomers and Oligomers»

30, Khojaly Av., Baku



S. A. Mammadkhanova
Institute of Petrochemical Processes named after Y.H. Mamedaliyev National Academy of Sciences; Azerbaijan State University of Oil and Industry
Azerbaijan

Sevinj A. Mammadkhanova, doctor of chemical sciences, professor, dean of the Chemical-Technological faculty

30, Khojaly Av., Baku

20, Azadliq av., Baku



A. B. Abdullazade
Azerbaijan State University of Oil and Industry
Azerbaijan

Aisel B. Abdullazade, graduate student

20, Azadliq av., Baku



D. B. Agamaliyeva
Institute of Petrochemical Processes named after Y.H. Mamedaliyev National Academy of Sciences
Azerbaijan

Durna B. Agamaliyeva, Ph.D. in Chemistry, leading researcher

30, Khojaly Av., Baku



S. A. Seidova
Institute of Petrochemical Processes named after Y.H. Mamedaliyev National Academy of Sciences
Azerbaijan

Sabina A. Seidova, senior researcher

30, Khojaly Av., Baku



N. M. Mammadova
Institute of Petrochemical Processes named after Y.H. Mamedaliyev National Academy of Sciences
Azerbaijan

Narmin M. Mammadova, senior researcher

30, Khojaly Av., Baku



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Review

For citations:


Ibragimova M.J., Mammadkhanova S.A., Abdullazade A.B., Agamaliyeva D.B., Seidova S.A., Mammadova N.M. Influence of oligomethylenaryl sulphonates based on the light gas oil of catalytic cracking on the process of biocorrosion. Theory and Practice of Corrosion Protection. 2020;25(4):18-25. (In Russ.) https://doi.org/10.31615/j.corros.prot.2020.98.4-2

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ISSN 1998-5738 (Print)
ISSN 2658-6797 (Online)